Question 7 of 34intermediate💡 UnderstandShort Answer2 marks

Explain why alkyl groups act as electron donors when attached to a π system.

Correct Answer

Alkyl groups act as electron donors when attached to a π\pi system due to hyperconjugation. When an alkyl group is attached to a π\pi system (such as a positively charged carbon atom in a carbocation), the electrons from the adjacent σ\sigma bond of the alkyl group overlap with the π\pi system.

This overlap allows the electron density from the adjacent σ\sigma bond to be donated into the π\pi system, which helps in dispersing the positive charge and stabilising the structure. Therefore, the greater the number of alkyl groups attached to the positively charged carbon atom, the greater is the hyperconjugation interaction and the overall stabilisation of the cation.

Exercise: EXERCISES | Q: 8.10
For More Understanding

Explanation

The textbook context explains that alkyl groups are electron-donating groups. When attached to a positively charged carbon atom (a π system), the adjacent σ bond of the alkyl group undergoes hyperconjugation. This overlap transfers electron density from the σ bond into the π system, dispersing the positive charge and stabilising the carbocation.