Predict if the solutions of the following salts are neutral, acidic or basic: NaCl, KBr, NaCN, NHNO, NaNO and KF
(KBr) Neutral
(KF) Basic
(NaCl) Neutral
(NaCN) Basic
(NaNO2) Basic
(NH4NO3) Acidic
Explanation
The nature of a salt solution depends on the strength of the parent acid and base. Salts formed from strong acids and strong bases do not hydrolyse and are neutral. Salts of weak acids and strong bases hydrolyse to produce OH⁻ ions, making the solution basic. Salts of strong acids and weak bases hydrolyse to produce H⁺ ions, making the solution acidic.
Solution Steps
NaCl and KBr are salts of strong acids (HCl, HBr) and strong bases (NaOH, KOH). Their ions simply get hydrated and do not hydrolyse, so their solutions are neutral.
NaCN, NaNO2, and KF are salts of weak acids (HCN, HNO2, HF) and strong bases (NaOH, KOH). Their anions undergo hydrolysis to produce OH⁻ ions, making their solutions basic.
NH4NO3 is a salt of a strong acid (HNO3) and a weak base (NH4OH). Its cation undergoes hydrolysis to produce H⁺ ions, making the solution acidic.