Question 6 of 9intermediate💡 UnderstandMCQ1 mark

Carbon, silicon and germanium have four valence electrons each. These are characterised by valence and conduction bands separated by energy band gap respectively equal to (Eg)C(E_g)_{C}, (Eg)Si(E_g)_{Si} and (Eg)Ge(E_g)_{Ge}. Which of the following statements is true?

Exercise: EXERCISES | Q: 14.3 | (Page Page 19)
For More Understanding

Explanation

The context clearly states: 'For C (diamond), Si and Ge, the energy gaps are 5.4 eV, 1.1 eV and 0.7 eV, respectively.' This means (Eg)C=5.4(E_g)_{C} = 5.4 eV, (Eg)Si=1.1(E_g)_{Si} = 1.1 eV, and (Eg)Ge=0.7(E_g)_{Ge} = 0.7 eV. Therefore, (Eg)C>(Eg)Si>(Eg)Ge(E_g)_{C} > (E_g)_{Si} > (E_g)_{Ge}, which corresponds to option (C). The energy gap decreases as we move down Group IV elements from Carbon to Germanium.

Solution Steps

  1. Step 1: From the context, identify the energy gap values: (Eg)C=5.4(E_g)_{C} = 5.4 eV, (Eg)Si=1.1(E_g)_{Si} = 1.1 eV, (Eg)Ge=0.7(E_g)_{Ge} = 0.7 eV

  2. Step 2: Arrange in descending order: 5.4 eV > 1.1 eV > 0.7 eV

  3. Step 3: Write the inequality: (Eg)C>(Eg)Si>(Eg)Ge(E_g)_{C} > (E_g)_{Si} > (E_g)_{Ge}

  4. Step 4: Match with option (C)