Why are compounds more stable than towards oxidation to their +3 state?
has a half-filled configuration which is particularly stable due to maximum exchange energy. This makes it difficult to remove an electron from , giving it a high third ionisation enthalpy. Hence, resists oxidation to .
In contrast, has a configuration. Upon oxidation to , it attains a stable half-filled configuration. The third ionisation enthalpy of Fe is lower than that of Mn, making more easily oxidized to .
Thus, compounds are more stable than towards oxidation to their +3 state.
Explanation
The textbook explains this in section 4.3.6 discussing trends in / standard electrode potentials. The key concept is that half-filled configurations have extra stability due to exchange energy (explained in the context about Hund's rule and parallel spins). already has this stable configuration, so it resists losing an electron. () readily loses an electron to achieve the stable configuration as . The context explicitly states that 'the third ionisation enthalpy of Fe is lower than that of Mn' and that '() is particularly stable' while '()' has extra stability.