Question 1 of 34intermediate🔧 ApplyShort Answer3 marks

Write the formulas for the following coordination compounds:

(i)

tetraamminediaquacobalt(III) chloride

Answer

[Co(NH₃)₄(H₂O)₂]Cl₃

(ii)

potassium tetracyanidonickelate(II)

Answer

K₂[Ni(CN)₄]

(iii)

tris(ethane–1,2–diamine) chromium(III) chloride

Answer

[Cr(en)₃]Cl₃

(iv)

amminebromidochloridonitrito-N-platinate(II)

Answer

[Pt(NH₃)BrCl(NO₂)]⁻

(v)

dichloridobis(ethane–1,2–diamine)platinum(IV) nitrate

(vi)

iron(III) hexacyanidoferrate(II)

Answer

Fe₄[Fe(CN)₆]₃

Explanation

The formulas are derived using IUPAC nomenclature rules from the context. For cationic complexes, the counter anion is written outside the square brackets. For anionic complexes (indicated by '-ate' suffix like nickelate, ferrate, platinate), the complex is placed in brackets with the counter cation outside. The oxidation state determines the overall charge, and ligands are listed alphabetically within the coordination entity.