The half-life for radioactive decay of is 5730 years. An archaeological artifact containing wood had only 80% of the found in a living tree. Estimate the age of the sample.
Radioactive decay is a first-order reaction. To estimate the age of the sample, we use the integrated rate law equation.
Step 1: Calculate the rate constant (). For a first-order reaction, the relationship between half-life and rate constant is given by:
Given years.
Step 2: Use the integrated rate law. The integrated rate law for a first-order reaction is:
Given that the artifact has 80% of the found in a living tree, we can assume the initial concentration and the final concentration .
Step 3: Calculate the age (). Substituting the values into the equation:
The estimated age of the sample is 1845 years.
Explanation
This question applies the concept of first-order kinetics to radioactive dating. The context provides the formula for the half-life of a first-order reaction () and the integrated rate law (). By calculating the rate constant from the half-life and substituting the ratio of remaining Carbon-14 into the integrated rate equation, the age of the artifact is determined.
Solution Steps
Step 1: Calculate the rate constant () using the half-life formula .
Step 2: Set up the integrated rate law equation .
Step 3: Substitute , , and the calculated value to solve for time .