Question 29 of 39intermediate🔧 ApplyShort Answer2 marks

Give IUPAC names of the following ethers: (i) C₂H₅OCH₂–CH(CH₃)–CH₃ (ii) CH₃OCH₂CH₂Cl (iii) O₂N–C₆H₄–OCH₃(p) (iv) CH₃CH₂CH₂OCH₃

(i)
Answer

1-Ethoxy-2-methylpropane

(ii)
Answer

1-Chloro-2-methoxyethane

(iii)
Answer

1-Methoxy-4-nitrobenzene

(iv)
Answer

1-Methoxypropane

Explanation

According to IUPAC nomenclature, ethers are named as alkoxyalkanes where the larger alkyl group is chosen as the parent hydrocarbon. For compound (i), the larger group is the 4-carbon branched chain (isobutyl), making propane the parent with ethoxy at position 1 and methyl at position 2. For (ii), ethane is the parent chain with methoxy and chloro substituents; alphabetically 'chloro' comes before 'methoxy', so chloro gets position 1. For (iii), methoxybenzene (anisole) is the parent with nitro at para position (position 4). For (iv), propane is the parent with methoxy at position 1, matching the example in Table 7.2.