An air bubble of volume 1.0 cm³ rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
The volume of the air bubble at the surface is approximately 5.3 cm³.
Explanation
This problem applies the ideal gas law to a situation where both pressure and temperature change. The key insight is that for a fixed amount of gas, P₁V₁/T₁ = P₂V₂/T₂. Students must recognize that the pressure at the bottom of the lake includes both atmospheric pressure and the pressure due to the water column (P = P₀ + ρgh). The context provides the atmospheric pressure value (1 atm = ⁵ Pa) from the molar volume discussion.
Solution Steps
Step 1: Convert temperatures to Kelvin T₁ = 12 °C = 12 + 273 = 285 K T₂ = 35 °C = 35 + 273 = 308 K
Step 2: Calculate pressure at the bottom of the lake P₁ = P₀ + ρgh = ⁵ + ( × 40) P₁ = ⁵ + ⁵ = ⁵ Pa
Step 3: Identify pressure at the surface P₂ = P₀ = ⁵ Pa
Step 4: Apply the ideal gas law for constant amount of gas Using P₁V₁/T₁ = P₂V₂/T₂ V₂ = (P₁V₁T₂)/(P₂T₁)
Step 5: Substitute values and calculate V₂ = (⁵ × ⁻⁶ × 308)/(⁵ × 285) V₂ = 1518.44/⁻⁶ m³ V₂ ⁻⁶ m³ 5.3 cm³