Question 17 of 62intermediate🔧 ApplyNumerical2 marks

Calculate the wavenumber for the longest wavelength transition in the Balmer series of atomic hydrogen.

Correct Answer

1.523×104 cm−11.523 \times 10^4 \text{ cm}^{-1}

Exercise: EXERCISES | Q: 2.17 | (Page 41)
For More Understanding

Explanation

The longest wavelength transition corresponds to the lowest energy transition. In the Balmer series, the lower energy level is n1=2n_1 = 2. The lowest energy transition occurs when the electron drops from the nearest higher energy level, which is n2=3n_2 = 3. Using the Rydberg formula provided in the text, we can calculate the wavenumber for this transition.

Solution Steps

  1. Step 1: For the Balmer series, n1=2n_1 = 2. The longest wavelength transition corresponds to the minimum energy transition, which occurs at the lowest possible value of n2n_2. Thus, n2=3n_2 = 3.

  2. Step 2: Using the Rydberg formula for wavenumber: νˉ=109,677(1n12−1n22) cm−1\bar{\nu} = 109,677 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \text{ cm}^{-1}.

  3. Step 3: Substitute n1=2n_1 = 2 and n2=3n_2 = 3 into the formula: νˉ=109,677(122−132) cm−1\bar{\nu} = 109,677 \left( \frac{1}{2^2} - \frac{1}{3^2} \right) \text{ cm}^{-1}.

  4. Step 4: Calculate the values inside the bracket: 14−19=9−436=536\frac{1}{4} - \frac{1}{9} = \frac{9 - 4}{36} = \frac{5}{36}.

  5. Step 5: Multiply by the Rydberg constant: νˉ=109,677×536 cm−1=15232.92 cm−1\bar{\nu} = 109,677 \times \frac{5}{36} \text{ cm}^{-1} = 15232.92 \text{ cm}^{-1}, which can be written as 1.523×104 cm−11.523 \times 10^4 \text{ cm}^{-1}.