Calculate the wavenumber for the longest wavelength transition in the Balmer series of atomic hydrogen.
Explanation
The longest wavelength transition corresponds to the lowest energy transition. In the Balmer series, the lower energy level is . The lowest energy transition occurs when the electron drops from the nearest higher energy level, which is . Using the Rydberg formula provided in the text, we can calculate the wavenumber for this transition.
Solution Steps
Step 1: For the Balmer series, . The longest wavelength transition corresponds to the minimum energy transition, which occurs at the lowest possible value of . Thus, .
Step 2: Using the Rydberg formula for wavenumber: .
Step 3: Substitute and into the formula: .
Step 4: Calculate the values inside the bracket: .
Step 5: Multiply by the Rydberg constant: , which can be written as .