Question 10 of 31intermediate🔧 ApplyShort Answer3 marks

Permanganate(VII) ion, MnO₄⁻ in basic solution oxidises iodide ion, I⁻ to produce molecular iodine (I₂) and manganese (IV) oxide (MnO₂). Write a balanced ionic equation to represent this redox reaction.

Correct Answer

6I−(aq)+2MnO4−(aq)+4H2O(l)→3I2(s)+2MnO2(s)+8OH−(aq)6\text{I}^-(\text{aq}) + 2\text{MnO}_4^-(\text{aq}) + 4\text{H}_2\text{O}(\text{l}) \rightarrow 3\text{I}_2(\text{s}) + 2\text{MnO}_2(\text{s}) + 8\text{OH}^-(\text{aq})

Exercise: Problem 7.10 | Q: Problem 7.10 | (Page Page 14)
For More Understanding

Explanation

To balance the redox reaction in a basic medium, we first split it into oxidation and reduction half-reactions. After balancing atoms and charges in an acidic medium, we neutralize H+\text{H}^+ ions by adding OH−\text{OH}^- ions to both sides, converting them into water. Finally, we balance the electrons and add the half-reactions together.

Solution Steps

  1. Step 1: Write the skeletal ionic equation: MnO4−(aq)+I−(aq)→MnO2(s)+I2(s)\text{MnO}_4^-(\text{aq}) + \text{I}^-(\text{aq}) \rightarrow \text{MnO}_2(\text{s}) + \text{I}_2(\text{s})

  2. Step 2: Write the half-reactions. Oxidation half: I−(aq)→I2(s)\text{I}^-(\text{aq}) \rightarrow \text{I}_2(\text{s}). Reduction half: MnO4−(aq)→MnO2(s)\text{MnO}_4^-(\text{aq}) \rightarrow \text{MnO}_2(\text{s})

  3. Step 3: Balance atoms in the oxidation half-reaction: 2I−(aq)→I2(s)2\text{I}^-(\text{aq}) \rightarrow \text{I}_2(\text{s}). For the reduction half, balance O with H2O\text{H}_2\text{O} and H with H+\text{H}^+: MnO4−(aq)+4H+(aq)→MnO2(s)+2H2O(l)\text{MnO}_4^-(\text{aq}) + 4\text{H}^+(\text{aq}) \rightarrow \text{MnO}_2(\text{s}) + 2\text{H}_2\text{O}(\text{l})

  4. Step 4: Convert to basic medium by adding 4OH−4\text{OH}^- to both sides of the reduction half-reaction: MnO4−(aq)+4H2O(l)→MnO2(s)+2H2O(l)+4OH−(aq)\text{MnO}_4^-(\text{aq}) + 4\text{H}_2\text{O}(\text{l}) \rightarrow \text{MnO}_2(\text{s}) + 2\text{H}_2\text{O}(\text{l}) + 4\text{OH}^-(\text{aq}). Simplifying water gives: MnO4−(aq)+2H2O(l)→MnO2(s)+4OH−(aq)\text{MnO}_4^-(\text{aq}) + 2\text{H}_2\text{O}(\text{l}) \rightarrow \text{MnO}_2(\text{s}) + 4\text{OH}^-(\text{aq})

  5. Step 5: Balance charges with electrons. Oxidation: 2I−(aq)→I2(s)+2e−2\text{I}^-(\text{aq}) \rightarrow \text{I}_2(\text{s}) + 2\text{e}^-. Reduction: MnO4−(aq)+2H2O(l)+3e−→MnO2(s)+4OH−(aq)\text{MnO}_4^-(\text{aq}) + 2\text{H}_2\text{O}(\text{l}) + 3\text{e}^- \rightarrow \text{MnO}_2(\text{s}) + 4\text{OH}^-(\text{aq}). Multiply oxidation by 3 and reduction by 2 to equalize electrons.

  6. Step 6: Add the half-reactions and cancel electrons to get the final balanced equation: 6I−(aq)+2MnO4−(aq)+4H2O(l)→3I2(s)+2MnO2(s)+8OH−(aq)6\text{I}^-(\text{aq}) + 2\text{MnO}_4^-(\text{aq}) + 4\text{H}_2\text{O}(\text{l}) \rightarrow 3\text{I}_2(\text{s}) + 2\text{MnO}_2(\text{s}) + 8\text{OH}^-(\text{aq})