Permanganate(VII) ion, MnO₄⁻ in basic solution oxidises iodide ion, I⁻ to produce molecular iodine (I₂) and manganese (IV) oxide (MnO₂). Write a balanced ionic equation to represent this redox reaction.
Explanation
To balance the redox reaction in a basic medium, we first split it into oxidation and reduction half-reactions. After balancing atoms and charges in an acidic medium, we neutralize ions by adding ions to both sides, converting them into water. Finally, we balance the electrons and add the half-reactions together.
Solution Steps
Step 1: Write the skeletal ionic equation:
Step 2: Write the half-reactions. Oxidation half: . Reduction half:
Step 3: Balance atoms in the oxidation half-reaction: . For the reduction half, balance O with and H with :
Step 4: Convert to basic medium by adding to both sides of the reduction half-reaction: . Simplifying water gives:
Step 5: Balance charges with electrons. Oxidation: . Reduction: . Multiply oxidation by 3 and reduction by 2 to equalize electrons.
Step 6: Add the half-reactions and cancel electrons to get the final balanced equation: