Question 22 of 32intermediate🔍 AnalyzeShort Answer2 marks

Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why? (a) 1s and 1s (b) 1s and 2pₓ; (c) 2pᵧ and 2pᵧ (d) 1s and 2s.

(A)
(B)
(C)
(D)

Explanation

Option C is correct because when the x-axis is the internuclear axis, the overlap of 2py2p_y and 2py2p_y orbitals results in a pi (π\pi) bond, not a sigma (σ\sigma) bond. Sigma molecular orbitals are symmetrical around the bond-axis, whereas pi molecular orbitals are not symmetrical. The 2py2p_y orbitals have positive lobes above and negative lobes below the molecular plane, making them unsuitable for sigma bonding along the x-axis.